I play at home with headphones, I don't plan on currently playing in a band or on stage. Not for now.

So should I buy pedals to go with my Line 6 amp, I also own a Boss Micro BR. Or would a pod be better?

which line 6 amp?
either way, chances are its a modelling amp. so it already had built-in effects and pedals won't sound good on it.
Ibanez S320 with Dimarzio Fred + Seymour Duncan 59-> Weeping Demon Wah -> Ibanez TS-7 -> Homemade iBoost x3 -> Keeley DS-1 -> Visual Sound H2O -> MXR Ten Band -> Traynor YCV20