I have a V-ampire XL210 by Behringer it has 125 preset effects and I have Digitech RP 80 that has 40 preset effects and 40 programable channels so that brings my effects total to 205 possible effects. I can arrange these effects in any order, but i don't know where to start. I play anything from Roy Orbison to Green Day. Can anyone give me any suggestions on the order in which I should arrange my effect. Of course I only use a hand full of them.

filters - compression - wah - distortion - amp - EQ - modulations - delay - reverb

usually the recommended order, although theres plenty of room here and there for experimenting.

But honestly dude, don't take my word for it or anyone elses.
Just experiment and see what you like the best, you can come up with some pretty unique sounds.