Is the sound from an amp different if it sits on the ground or if it is on a stand.
No. But it may seem louder because the speaker will be pointed directly at you.
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It may sound different to you too. But the audience will still hear the same thing. It makes little difference one you're farther away.
Hahahaha this is similar to the question "If a tree falls in a forest but no one is there to hear it, does it make a sound"

Yes: the tone will be different to YOU if it is on a stand because of the way the speaker projects sound

No: technically there isn't any change in the sound just by moving the amps physical position, just a change in the way you hear it