So I see people on here all the time talking about having their pedals set at 10:00 or 12:00. What exactly does that mean? Do I look at the dial like a clock and adjust accordingly?? If so how would you get a 6 o'clock. That's all I wanted to know.

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Yes, do look at it as a clock face. There isn't a 6:00 on pedals/amps, the furthest the pot can turn is at about 5:00
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Well, take this tubescreamer for example.

The drive is at 2, the level is at 10, and the tone is at 4. It corresponds to a clock face, the knob being the hour hand.

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