I'm looking for somewhat older RPG's for PC's. Basically if it can run on an earlier version of XP then it's good. All I know is that Morrowind works on it.

Do not suggest anything on emulators, I'm looking for PC exclusives.
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Baldurs Gate 1&2
Icewind Dale
Neverwinter Nights
Arcanum: Of Steamworks and Magic Obscura
Planescape: Torment
Fallout 3 will probably run on it.

It's much better than Fallout 1 or 2.
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The Elder Scrolls II: Daggerfall

its available for free on the publishers website

its an insanely huge game as well

This. And Elder Scrolls Arena aswell, you'll need to use a DoSBox which can be downloaded for free also. (Just incase you didn't know)
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For her gaze, it blisters;
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