I have decided to buy a Vox AD30VT, but there is one thing I would like to know before I buy it. The amp has two channels, so can I choose an effect and amp for one channel and a different effect and amp model for the second channel? I want to have a rhythm channel and a lead channel with different effects on, but I'm not sure if it's possible to have different effects on two channels.
Yes you can choose one amp model and effect for each channel.

Basically the channel copies whatever you have set on the amp at the time except master volume.
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Thanks a lot, that's all I wanted to know, now I'm sure I'm gonna buy it