#2
You wouldn't need a pedal to get a Metallica tone out of the VK. I brought my Metal Muff into the store and tested that on the clean channel of the VK, and then tried out the OD channel w/o the pedal, not much difference.
#5
Valveking would probably be better, you wouldn't really need the Metal Muff then. The Metal Muff isn't very good though, but if you like it then whatever.
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#7
Well if you like the distortion sound you're getting then I'd suggest getting an amp geared more toward cleans. And just use the pedal as you please. I think the onboard distortion on the VK is better IMO though, but hey it's your ear.