I've just received a second hand acrylic warlock which has a chipped headstock (in the usual bc rich place). I've fixed more headstocks than I can remember but I'm a complete virgin when it comes to dealing with lucite.

Any solutions and/or ideas would be greatly appreciated.
You might be able to mix up some sort of clear resin.

But it probably wouldn't match the Warlock's acrylic, and you'd see the join etc.

Unless it's really bad, I'd just leave it.
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Depends on the kind of break and if you have all the pieces. Unless it is a clean break and you have all the pieces, I wouldn't bother.
Fixing clear acrylic is pretty much impossible. There wont be a chip but you will see where it was.